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Development of a desalination membrane bioinspired by mangrove roots for spontaneous filtration of sodium ions

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조회 10회 작성일 25-05-08 15:24

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Journal ACS Nano
Name Kiwoong Kim, Hyejeong Kim, Jae Hong Lim, and Sang Joon Lee
Year 2016

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The shortage of available fresh water is one of the global issues presently faced by humanity. To determine a solution to this problem, the survival strategies of plants have been examined. In this study, a nature-inspired membrane with a highly charged surface is proposed as an effective membrane for the filtration of saline water. To mimic the desalination characteristics of mangrove roots, a macroporous membrane based on polyethylene terephthalate is treated with polyelectrolytes using a layer-by-layer deposition method. The fabricated membrane surface has a highly negative charged ζ-potential value of −97.5 ± 4.3 mV, similar to that of the first layer of mangrove roots. Desalination of saline water using this membrane shows a high salt retention rate of 96.5%. The highly charged surface of the membrane may induce a relatively thick and stable ion depletion zone in front of the membrane. As a result, most co-ions are repelled from the membrane surface, and counterions are also rejected by virtue of their electroneutrality. The water permeability is found to be 7.60–7.69 L/m2·h, which is 10 times higher than that of the reverse osmosis desalination method. This nature-inspired filtration membrane exhibits steady desalination performance over 72 h of operation, successfully demonstrating the stable filtration of saline water. This nature-inspired membrane is applicable to the design of a small-scale, portable, and energy-free desalination device for use in third-world countries or small villages.

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